Advancing
Thursday, 3 July 2014
Thursday, 6 February 2014
How to easily overcome hiccups
Focusing on easy breathing and simultaneously "simulating" small pressure in the area of abdomen. The hiccups fades away in a moment.
Tuesday, 4 February 2014
Preaparing Ag electrode
How to prepare silver chloride electrode
Procedure:| 1) | pure $Ag$ wire |
| 2) | surface cleaning in $HNO_3$ |
| 3) | oxide removing in concentrated $NH_3$ |
| 4) | electroless deposition in mixture of $FeCl_3$ 0.25 mol/l and $HCl$ 0.20 mol/l |
Alternatively the $AgCl$ layer can be formed electrochemically in acidic NaCl solution (addition of $HCl$) at low current density (up to 1 A/$dm^2$ ). Higher concentrations of $HCl$ will cause the dissolution of $AgCl$ film.
Fundamentals of physical chemistry
Wait for it
| Heat capacity | Work |
|---|---|
| $c_p=\left(\frac{\partial H}{\partial T}\right)_p$ | $dW=-pdV$ |
| $c_V=\left(\frac{\partial U}{\partial T}\right)_V$ |
Laws of thermodynamics
| 1st | $dU=dQ+dW$ |
|---|---|
| 2nd | $ dS= \frac{dQ}{T} $ |
| 3rd | $\lim_{T \to 0}=0$ |
Simplified definitions of energies
| $dU=dQ+dW$ | |
| $ dH= dU+d(pV) $ | |
| $dF=dU-d(TS)$ | |
| $dG=dH-d(TS)$ | |
| $dH=TdS-pdV+pdV+Vdp$ | |
| $dF=TdS-pdV-TdS-SdT$ | |
| $dG=TdS+Vdp-TdS-SdT$ | |
| $dH=TdS+Vdp$ | |
| $dF=-pdV-SdT$ | |
| $dG=Vdp-SdT$ | |
| $dU=TdS-pdV$ | |
| $ dH= TdS+Vdp $ | |
| $ dF=-SdT-pdV$ | |
| $dG=-Sdt+Vdp$ |
Omega (angular frequency) and electrical resistance and capacitance
Derivation: how is angular frequency ralated to electrical resistance and capacitance
simplify notation
$ Q=I \cdot t \qquad [Q]=C,\quad [I]=A,\quad [t]=s $
$ I=\frac{E}{R} \qquad [E]=V,\quad [I]=A,\quad [R]=\Omega $
$ C=\frac{Q}{E} \qquad [E]=V,\quad [Q]=C,\quad [C]=F $
$ I=\frac{Q}{t} \qquad E=\frac{Q}{C} $
$ I=\frac{E}{R} \mid E=\frac{Q}{C} \quad \rightarrow \quad I=\frac{Q}{R \cdot C} $
$ I=\frac{Q}{R \cdot C} \mid I=\frac{Q}{t} \quad \rightarrow \quad \frac{Q}{t}=\frac{Q}{R \cdot C} $
$ \frac{Q}{t}=\frac{Q}{R \cdot C} \mid :Q \quad \rightarrow \quad \frac{1}{t}=\frac{1}{R \cdot C} $
$ \frac{1}{t}=f \qquad [t]=s,\quad [f]=\frac{1}{s} $
$ \omega = 2 \Pi f \qquad [\omega]=\frac{1}{s},\quad [\Pi]=\varnothing ,\quad [f]=\frac{1}{s} $
$ \frac{1}{t}=\frac{1}{R \cdot C} = \omega $